Volume No. :   8

Issue No. :  4

Year :  2016

ISSN Print :  0975-4393

ISSN Online :  2349-2988


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Complexation Behavior of 1-Phenyl-2,3-dimethyl-4-(benzylamino) pyrazol-5-one Schiff Base Ligand with Manganese ion



Address:   K.O. Eberendu, I.E. Otuokere
Department of Chemistry, Michael Okpara University of Agriculture, Umudike, Nigeria
*Corresponding Author
DOI No: 10.5958/2349-2988.2016.00029.2

ABSTRACT:
Complexation behaviour of the Schiff base ligand, 1-phenyl-2,3-dimethyl-4-(benzylamino)pyrazole-5-one with manganese metal ion has been studied. The Schiff base ligand, 1-phenyl-2,3-dimethyl-4-(benzylamino)pyrazol-5-one was synthesized by the condensation reaction of 4-aminoantipyrine and benzaldehyde. The ligand and complex were characterized based on their colour, melting point, solubility, infrared and mass spectral analyses. Spectroscopic analyses suggested the involvement of C=N, C=O and chloride ions in chelation. A tetrahedral geometry was suggested for the manganese complex.
KEYWORDS:
1-phenyl-2,3-dimethyl-4-(benzylamino)pyrazol-5-one, manganese, mass spectra, infrared, Schiff base.
Cite:
K.O. Eberendu, I.E. Otuokere. Complexation Behavior of 1-Phenyl-2,3-dimethyl-4-(benzylamino) pyrazol-5-one Schiff Base Ligand with Manganese ion. Research J. Science and Tech. 2016; 8(4):199-203.
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